First, there is one Demimask in every settlement you unlock as you travel through the open world. Use Revelio to spot them (inside certain buildings). You will receive three more demimasks according to the plot of the game by completing Moon's task. You will receive 11 Demimasks in the open world by exploring 11 settlements.
There are 9 more at Hogsmeade and 10 at Hogwarts (not counting those three).
Demimask #1: Flying flames in Professor Fig's office. Climb the stairs to the classroom and enter Fig's office. The Demimask is on the table next to the fireplace.
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Demimask #2: A flying flame in the Transfiguration class. Turn around and enter the double doors on the left. Climb up the small stairs and then go down a few flights to the right until you see an armored horse. Turn the corner and go straight to the sleeping dragon statue. Open the first level lock on the door on the right and you will see a figurine on the furniture next to the door.
Demimask #3: Defense Against the Dark Arts. Climb down the stairs until you reach the lower ground. Open the locked door of the second level on the left, and look for the figurine on the table.
Demimask #4: The flying flames of the Great Hall. Head to the right of the Hufflepuff's dining table and open the first level's locked door.
Demimask #5: A flying flame in the library. Turn around and go to the Restricted Section (closed area). Climb down and jump over the first hole to the floor below. To the right of the chest with the eye you will see a lamp and a figurine.
Demimask #6: A flying flame in the Potions classroom. Go through the double doors and down the spiral staircase on the left. Open the first level locked door and then go down the corridor until you can open another door on the left. The figurine is in a small room under the Potions classroom.
Demimask #7: A flying flame in Divination class. Climb up the spiral staircase, climb up the rope ladder and look for the item on Professor Onai's desk.
Demimask #8: A flying flame in the Beast Study Classroom. Turn around and open the second level door to enter the building. Go inside and go down the stairs to get this figurine.
Demimask #9: The flying flames of the north exit of Hogwarts. Turn around and find the first level locked door on the ground behind the stairs. The figurine is in a small room inside.
Demimask #10: A flying flame in the courtyard of the Clock Tower. Turn around and go through the door behind the gate and over the bridge through the next double doors. Head left and then open the first level lock to access the restroom. Come through?Go through a booth with a hole to find a secret room with a figurine.